Epoxide Rearrangement. IV. Isomerization of Cyclohexene and 1-Methyl-cyclohexene Oxides over Solid Acids and Bases in Gas Phase
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Stoichiometry and Kinetics of Gas Phase Cyclohexene Epoxidation by a Silica-Supported tert- Butylperoxidititanium Complex
Peroxo and alkylperoxo metal complexes are presumed intermediates in the homogeneous and heterogeneous catalytic epoxidations of olefins. Both solid and soluble versions containing high valent, d° transition metal ions activate peroxides heterolytically, thereby facilitating oxygen atom transfer to electron-rich substrates (1). However, mechanistic studies have been undertaken largely with the ...
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Investigating the composition of organic aerosol resulting from cyclohexene ozonolysis: low molecular weight and heterogeneous reaction products J. F. Hamilton, A. C. Lewis, J. Reynolds, L. J. Carpenter, and A. Lubben Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK Bruker Daltonics, Banner Lane, Coventry, CV4 9GH, UK Received: 26 April 2006 – Accepted: 16 May 2006 – ...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1976
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.49.563