Enlightening the journey of metal-organic framework (derived) catalysts during the oxygen evolution reaction in alkaline media via operando X-ray absorption spectroscopy

نویسندگان

چکیده

The development of catalysts with enhanced activity for the oxygen evolution reaction (OER) compared to traditionally used metal oxide is crucial further commercialization electrolyzers. Because their high surface area and adjustable pore structure, metal-organic framework (MOF)-based represent a promising alternative. During OER in alkaline media, initial MOF structure susceptible transformations including decomposition organic backbone and/or formation oxide, hydroxide oxyhydroxide intermediates. Hence, operando characterizations during are essential understand material's progressive changes extract catalytic mechanism. This article discusses existing X-ray absorption spectroscopy studies MOF(-derived) extracts important parameters future research regarding MOFs electrolysis.

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ژورنال

عنوان ژورنال: Current Opinion in Electrochemistry

سال: 2021

ISSN: ['2451-9103', '2451-9111']

DOI: https://doi.org/10.1016/j.coelec.2021.100845