Enhancing the Activity of Cu-MOR by Water for Oxidation of Methane to Methanol
نویسندگان
چکیده
As clean energy, methane has huge reserves and great development potential in the future. Copper zeolites are efficient oxidation of to methanol. Water been confirmed as a source oxygen regenerate copper-zeolite active sites enable selective anaerobic In this work, we report that methanol yield increased from 36 μmol/g (Cu-MOR1) 92 (Cu-MOR1-water) result water enhancing activity copper ion-exchange mordenite catalyst. We show for first time could convert inactive species into during catalyst activation. A combination XPS, FTIR, NMR results indicates dissociates then converts ZCuIIZ ZCuII(OH) (where Z framework O (Ofw) bonded one isolated Al T-site, i.e., 1Al) simultaneously produces Brönsted acid site This finding can be used tune state design highly catalysts
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ژورنال
عنوان ژورنال: Catalysts
سال: 2023
ISSN: ['2073-4344']
DOI: https://doi.org/10.3390/catal13071066