Emulsion Polymerization of 2-Cyano-1, 3-butadiene
نویسندگان
چکیده
منابع مشابه
Particle growth in butadiene emulsion polymerization. 4. The promoting effect of mercaptans
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The title compound, C(13)H(13)NO(4)S, is a racemic mixture of enanti-omers. Short intra-molecular contacts between sulfonyl O and ester carbonyl C atoms are observed [C⋯O = 2.881 (1), 2.882 (1) and 2.686 (1) Å], indicating the possibility of donor-acceptor inter-actions between these groups. The dihedral angle between the phenyl and cyclopropyl rings is 79.3 (1)°.
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In the title compound, C(7)H(7)N(2) (+)·NO(3) (-), all atoms except the methyl H atoms lie on a crystallographic mirror plane. The inter-layer distance, including that between aligned N atoms from alternating cations and anions in adjacent layers, is exceptionally short at 3.055 (1) Å. Two-dimensional C-H⋯O hydrogen-bonded networks link cations to anions, while C-H⋯N inter-actions link cations ...
متن کامل2-Cyano-1-methylpyridinium iodide
The cation in the title compound, C7H7N2 (+)·I(-), is planar (r.m.s. deviation for the nine fitted non-H atoms = 0.040 Å). The crystal packing is best described as undulating layers of cations and anions associated via C-H⋯I inter-actions.
متن کامل(E)-N-Benzyl-2-cyano-3-phenylacrylamide
In the title compound, C(17)H(14)N(2)O, the N-benzyl-formamide and phenyl groups are located on the opposite sides of the C=C bond, showing an E configuration; the terminal phenyl rings are twisted to each other at a dihedral angle of 63.61 (7)°. Inter-molecular classical N-H⋯N and weak C-H⋯O hydrogen bonds occur in the crystal structure.
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ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1958
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.61.1370