Electrochemistry in pyridine-IV. Chemical and electrochemical reduction of pyridine
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Electrochemistry in Pyridine-iv. Chemical and Electrochemical Reduction of Pyridine”
The cathodic polarographic wave observed for solutions of AlCl, in pyridine is due not to reduction of Al(III), but to reduction of the solvent, in which process Al(II1) plays an essential role, apparently by polarizing the pyridine through the formation of a Lewis acid-base adduct with the pyridine nitrogen. Macroscale electrolysis of pyridine solutions of AlCl, at a mercury cathode results in...
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ژورنال
عنوان ژورنال: Electrochimica Acta
سال: 1965
ISSN: 0013-4686
DOI: 10.1016/0013-4686(65)80005-6