Electroactive 1,5-benzodiazepines bearing either a tetrathiafulvalene or a ferrocene moiety
نویسندگان
چکیده
منابع مشابه
Electroactive gold nanoparticles protected by 4-ferrocene thiophenol monolayer.
Numerous reports have focused on ferrocene-terminated electroactive self-assembled monolayers (SAMs) on a flat Au surface but only a few on ferrocene SAMs on Au colloid. In this paper, we employ 4-ferrocene thiophenol as a novel capping agent to produce electroactive gold nanoparticles in consideration of the peculiar pi-conjugated structure. Transmission electron microscopy shows the narrow-di...
متن کاملf/sla from learner perspectives: a social activity or a cognitive process
in the past couple of decades sociocultural theory of sla and its implications in efl contexts have attracted attentions of research circles worldwide and aroused some controversies. firth and wagner (1997) have questioned the principles of the cognitive view which gives importance to mental constructs in favor of sociocultural view which highlights social and contextual constructs. but if soci...
15 صفحه اولReactions of nitroxides 15. Cinnamates bearing a nitroxyl moiety synthesized using a Mizoroki–Heck cross-coupling reaction
Cinnamic acid derivatives bearing a nitroxyl moiety (2,2,6,6-tetramethyl-1-oxyl-4-piperidyl 3-E-aryl acrylates) were synthesized in 30-100% yield using a Mizoroki-Heck cross-coupling reaction between 4-acryloyloxy-2,2,6,6-tetramethylpiperidine-1-oxyl and iodobenzene derivatives in the presence of palladium(II) acetate coordinated with a tri(o-tolyl)phosphine ligand immobilized in a polyurea mat...
متن کاملSynthesis of novel derivatives of chromenone bearing an N -carbamothioyl moiety as soybean 15-LOX inhibitors
Novel derivatives of chromenone bearing an N -carbamothioyl moiety were synthesized and evaluated for their soybean 15-LOX inhibitory activity. Synthesis of the target compounds was started from 7-hydroxy-2H -chromen-2-one. It was reacted with 1-fluoro-2(4)-nitrobenzene to obtain the corresponding nitrophenoxy-chromenone derivative. Reduction of the nitro group was achieved in the presence of Z...
متن کاملA Model of Irreversible Electro-Oxidation Inhibited by Either Adsorption or Surface Complexation of the Product
Theoretical models of irreversible electro-oxidation of dissolved reactant giving dissolved product on the stationary planar electrode are developed for the conditions of staircase cyclic voltammetry. In the first model it is assumed that the product is adsorbed on the electrode surface and that the adsorbate prevents the transfer of electrons. In the second model it is assumed that the electro...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Tetrahedron
سال: 2013
ISSN: 0040-4020
DOI: 10.1016/j.tet.2013.04.005