Efficient Assembly of 2,5,6-Substituted Pyrimidines via MgI2-Mediated Morita−Baylis−Hillman Reaction
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چکیده
منابع مشابه
Reaction of oxide radical ion ( O . ¡ ) with substituted pyrimidines
Pulse radiolysis technique has been used to investigate the reaction of oxide radical ion (O.¡) with 4,6-dihydroxy-2-methyl pyrimidine (DHMP), 2,4-dimethyl-6-hydroxy pyrimidine (DMHP), 5,6-dimethyl uracil (DMU) and 6-methyl uracil (MU) in strongly alkaline medium. The second-order rate constants for the reaction of O.¡ with these compounds are in the range 2–5£ 108 dm3mol¡1 s¡1. The transient a...
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Humans are exposed to various organic peroxides through chemical, pharmaceutical and cosmetic products. On photolysis, these peroxides produce alkoxyl radicals and hydroxyl radicals. The reaction of *OH radicals with DNA and its constituents have been extensively studied, but very little is known about the reactions of alkoxyl radicals with DNA and its constituents. In view of this, the oxidati...
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ژورنال
عنوان ژورنال: Journal of Combinatorial Chemistry
سال: 2010
ISSN: 1520-4766,1520-4774
DOI: 10.1021/cc100001e