Effect of Temperature and Substitution on Cope Rearrangement: A Symmetry Perspective
نویسندگان
چکیده
منابع مشابه
Effect of temperature and substitution on Cope rearrangement: a symmetry perspective.
Many reactions feature symmetry variation along the reaction path on the potential energy surface. The interconversion of the point group symmetry of the stationary points can be characteristic of these processes. Increasing the temperature, however, leads to the loss of symmetry in its traditional yes-no language. We find that in such cases the instantaneous distance of the molecular structure...
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چکیده ندارد.
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ژورنال
عنوان ژورنال: The Journal of Physical Chemistry A
سال: 2013
ISSN: 1089-5639,1520-5215
DOI: 10.1021/jp411044m