(E)-2-[(4-Ethoxyphenyl)iminomethyl]-4-methoxyphenol

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(E)-2-{4-[1-(Hydroxyimino)ethyl]phenyl­iminomethyl}-6-methoxyphenol mono­hydrate

In the title compound, C(16)H(16)N(2)O(3)·H(2)O, the benzene rings are nearly coplanar with each other, forming a dihedral angle of 4.46 (3)°. There is a strong intra-molecular O-H⋯N hydrogen bond which results in a six-membered ring. In the crystal, the mol-ecules are connected into a three-dimensional network via O-H⋯O and O-H⋯N inter-molecular hydrogen bonds, forming a centrosymmetric ring a...

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(E)-4-[(4-Bromo­phen­yl)imino­meth­yl]-2-meth­oxy­phenol

In the crystal structure of the title compound, C(14)H(12)BrNO(2), the dihedral angle between the rings is 37.87 (10)° and the mol-ecule has an E conformation about the central C=N bond. In the crystal, mol-ecules are connected by inter-molecular O-H⋯N hydrogen bonds into zigzag chains running parallel to the b axis. The packing also features C-H⋯O inter-actions.

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(E)-2-[(4-Ethoxy­phen­yl)imino­meth­yl]-4-methoxy­phenol

In the mol-ecule of the title compound, C(16)H(17)NO(3), the aromatic rings are oriented at a dihedral angle of 29.25 (8)°. An intra-molecular O-H⋯N hydrogen bond results in the formation of a nearly planar [maximum deviation 0.034 (13) Å] six-membered ring, which is oriented at dihedral angles of 0.91 (1) and 28.91 (12)° with respect to the aromatic rings. The title mol-ecule is a phenol-imine...

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2-[(E)-(4-Bromo­phenyl)imino­methyl]-4-chloro­phenol

In the title compound, C13H9BrClNO, the dihedral angle between the substituted benzene rings is 44.25 (11)°. There are strong intra-molecular O-H⋯N hydrogen bonds, which generate S(6) rings, and also inter-molecular Cl⋯Cl [3.431 (3) Å] and Br⋯ Br [3.846 (1) Å] contacts. The crystal packing a C-H⋯O and C-H⋯π inter-actions.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809040586