Dynamic nuclear polarization at high magnetic fields
نویسندگان
چکیده
منابع مشابه
Dynamic Nuclear Polarization of Biological Systems at High Magnetic Fields
Dynamic nuclear polarization methods were studied at high magnetic field strength and were applied to improve the sensitivity of the nuclear magnetic resonance spectroscopy of biological solids. Studies of the dynamics of electron-nuclear polarization transfer via the solid effect and thermal mixing at 5 Tesla are described for two systems: the free radical BDPA doped into polystyrene and the n...
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By applying a new technique for dynamic nuclear polarization involving simultaneous excitation of electronic and nuclear transitions, we have enhanced the nuclear polarization of the nitrogen nuclei in 15N@C60 by a factor of 10(3) at a fixed temperature of 3 K and a magnetic field of 8.6 T, more than twice the maximum enhancement reported to date. This methodology will allow the initialization ...
متن کاملDynamic nuclear polarization at high magnetic fields in liquids.
MPI for Biophysical Chemistry Göttingen, Am Fassberg 11, 37077 Göttingen, Germany b Free University Berlin, Inst. of Experimental Physics, Arnimallee 14, 14195 Berlin, Germany Magnetic Resonance Center (CERM) and Department of Chemistry, University of Florence, Via Luigi Sacconi 6, 50019 Sesto Fiorentino, Italy Bruker Biospin GmbH, Silberstreifen 4, 76287 Rheinstetten, Germany e Technische Univ...
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The goal of dynamic nuclear polarization (DNP) is to enhance NMR signals by transferring electron spin polarization to the nuclei. Although mechanisms such as the solid effect and thermal mixing can be used for DNP in the solid state, currently, the only practical mechanism in solutions is the Overhauser effect (OE), which usually arises due to dipolar relaxation between electrons and the nucle...
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During the three decades 1980-2010, magic angle spinning (MAS) NMR developed into the method of choice to examine many chemical, physical, and biological problems. In particular, a variety of dipolar recoupling methods to measure distances and torsion angles can now constrain molecular structures to high resolution. However, applications are often limited by the low sensitivity of the experimen...
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ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 2008
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.2833582