Dynamic Nuclear Polarisation Enhanced Solid-State Nuclear Magnetic Resonance Studies of Surface Modification of γ-Alumina
نویسندگان
چکیده
منابع مشابه
Solid State Nuclear Magnetic Resonance
In 2001, Mauri and Pickard introduced the gauge including projected augmented wave (GIPAW) method that enabled for the first time the calculation of all-electron NMR parameters in solids, i.e. accounting for periodic boundary conditions. The GIPAW method roots in the plane wave pseudopotential formalism of the density functional theory (DFT), and avoids the use of the cluster approximation. Thi...
متن کاملSolid-state nuclear magnetic resonance.
SCOPE This review focuses on developments and applications in the field of nuclear magnetic resonance of solids appearing in the literature between October 1999 and October 2001. The review emphasizes uses of solid-state NMR spectroscopy to answer questions about problems in certain areas of chemistry and materials science. As time passes, the use of solid-state techniques to address problems i...
متن کاملSolid State Nuclear Magnetic Resonance
A H–C frequency-selective REDOR (FS-REDOR) experiment is developed for measuring intramolecular H–C distances in uniformly C, N-labeled molecules. Theory and simulations show that the experiment removes the interfering homonuclear H–H, C–C and heteronuclear H–N, C–N dipolar interactions while retaining the desired heteronuclear H–C dipolar interaction. Our results indicate that this technique, ...
متن کاملExperimental and Theoretical Studies in Solid-state Nuclear Magnetic Resonance
Solid-state nuclear magnetic resonance (SSNMR) has proven to be a powerful tool for probing molecular structure and dynamics. Deuterium SSNMR is particularly useful due to the presence of anisotropic interactions whose motional averaging contributes structural and dynamical insight. The magnitude and type of molecular motion can be determined from analysis of solid echo deuterium lineshapes and...
متن کاملOxygen-17 dynamic nuclear polarisation enhanced solid-state NMR spectroscopy at 18.8 T.
We report 17O dynamic nuclear polarisation (DNP) enhanced solid-state NMR experiments at 18.8 T. Several formulations were investigated on the Mg(OH)2 compound. A signal enhancement factor of 17 could be obtained when the solid particles were incorporated into a glassy o-terphenyl matrix doped with BDPA using the Overhauser polarisation transfer scheme whilst the cross effect mechanism enabled ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Johnson Matthey Technology Review
سال: 2018
ISSN: 2056-5135
DOI: 10.1595/205651318x696765