Dry-column Vacuum Chromatographic Removal of Hg2+ from Wastewater Based on an Acridino-crown Ether-modified Spherical Silica Gel Adsorbent

نویسندگان

چکیده

Dry-column vacuum chromatographic technique is introduced for remediation of wastewater the first time. A previously prepared chemically modified silica gel containing covalently immobilized Hg2+-selective acridino-crown ether selector molecules was used as an adsorbent. Removal Hg2+ from highly contaminated river water carried out to study practical applicability. Adsorption capacity, preconcentration factor, pH-sensitivity and selectivity in separation were determined. The adsorbent proved be outstanding selectivity, only Ag+ Cu2+ interfered among 29 cations, inert toward organic contaminants, exhibited regenerability pH-independency between 3.0 ≤ pH 7.0. proposed method showed a moderate efficiency both adsorption (32 mg / 1 g adsorbent) (preconcentration factor 100). maximum 10 L ratio recommended upper limit described unique robustness simplicity compared conventional ion-chromatographic methods improved over physical interaction- or simple functional group-based adsorptions.

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ژورنال

عنوان ژورنال: Periodica Polytechnica Chemical Engineering

سال: 2023

ISSN: ['1587-3765', '0324-5853']

DOI: https://doi.org/10.3311/ppch.21563