Dissolution of Iron in Nonaqueous Formic Acid
نویسندگان
چکیده
منابع مشابه
Efficient dehydrogenation of formic acid using an iron catalyst.
Hydrogen is one of the essential reactants in the chemical industry, though its generation from renewable sources and storage in a safe and reversible manner remain challenging. Formic acid (HCO(2)H or FA) is a promising source and storage material in this respect. Here, we present a highly active iron catalyst system for the liberation of H(2) from FA. Applying 0.005 mole percent of Fe(BF(4))(...
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Formic acid (FA) is an attractive compound for H2 storage. Currently, the most active catalysts for FA dehydrogenation use precious metals. Here, we report a homogeneous iron catalyst that, when used with a Lewis acid (LA) co-catalyst, gives approximately 1,000,000 turnovers for FA dehydrogenation. To date, this is the highest turnover number reported for a first-row transition metal catalyst. ...
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We have measured new submillimeter-wave data around 600 GHz and around 1.1 THz for the C isotopologue of formic acid and for the two deuterium isotopomers; in each case for both the trans and cis rotamer. For cis-DCOOH and cis-HCOOD in particular only data up to 50 GHz was previously available. For all species the quality and quantity of molecular parameters has been increased providing new mea...
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ژورنال
عنوان ژورنال: CORROSION ENGINEERING
سال: 1981
ISSN: 0010-9355,1884-1155
DOI: 10.3323/jcorr1974.30.11_634