Directed Remote Aromatic Metalations: Mechanisms and Driving Forces
نویسندگان
چکیده
منابع مشابه
Directed remote aromatic metalations: mechanisms and driving forces.
Directed remote aromatic metalations are useful synthetic transformations allowing for rapid regioselective access to elaborate highly substituted carbocyclic aromatic and heteroaromatic systems. This review unravels the tangle of data reported on directed remote aromatic metalations. Through a careful analysis of critically selected examples, advanced rationalizations of remote metalation regi...
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Figure 1: Directed aromatic functionalization methods. The title of this Thematic Series brings to the minds of most organic chemists the beautifully logical aromatic electrophilic substitution (SEAr) [1-5] and, to a lesser extent, nucleophilic aromatic substitution (SNAr) [2,6,7] reactions as taught to many generations of students in their first organic chemistry courses [8] (Figure 1). Being ...
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ژورنال
عنوان ژورنال: Chemistry - A European Journal
سال: 2012
ISSN: 0947-6539
DOI: 10.1002/chem.201103920