Direct synthesis of non-breathing MIL-53(Al)(ht) from a terephthalate-based ionic liquid as linker precursor

Direct synthesis of non-breathing MIL-53(Al)(ht) from a terephthalate-based ionic liquid as linker precursor.

An organic imidazolium salt of terephthalic acid has been utilized as a linker precursor for the synthesis of an aluminum-based metal organic framework (MOF) with MIL-53(ht) structure. This material shows the predicted porosity in terms of nitrogen and hydrogen sorption without exhibiting the breathing effect typical for MIL-53(Al) materials.

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Direct synthesis of non-breathing MIL-53(Al)(ht) from a terephthalate-based ionic liquid as linker precursor

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