Diiodidobis(1-methylimidazole-κN3)cadmium(II)
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چکیده
منابع مشابه
N-Methylimidazole Promotes the Reaction of Homophthalic Anhydride with Imines
The addition of N-methylimidazole (NMI) to the reaction of homophthalic anhydride with imines such as pyridine-3-carboxaldehyde-N-trifluoroethylimine (9) reduces the amount of elimination byproduct and improves the yield of the formal cycloadduct, tetrahydroisoquinolonic carboxylate 10. Carboxanilides of such compounds are of interest as potential antimalarial agents. A mechanism that rationali...
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A method for the determination or 4-methylimidazole in caramel color, based on cationic separation of the sample by capillary isotachophoresis, is described. No pretreatment of the sample is necessary and the detection limit was found to be 5 ppm.
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Sensitized photooxidation of imidazoles in aqueous solution and in the presence of inorganic phosphate afforded organic phosphates with yields up to 30%. The major phosphorylated product of oxidation of 2-methylimidazole was isolated and identified as the monophosphate of 4,5-dihydroxy-2-methyl-imidazoline with pKa values of 2.0, 5.2, and 9.8. The compound is energy rich in aqueous solution and...
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The 351.1 nm photoelectron spectra of the N-methyl-5-pyrazolide anion and the N-methyl-5-imidazolide anion are reported. The photoelectron spectra of both isomers display extended vibrational progressions in the X2A' ground states of the corresponding radicals that are well reproduced by Franck-Condon simulations, based on the results of B3LYP/6-311++G(d,p) calculations. The electron affinities...
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The partition coefficients, Kmim, of N-methylimidazole (mim) in two-component systems composed of ionic liquid (IL) and a series of organic solvents immiscible with ILs (butyl acetate, ethyl acetate, tert-butyl methyl ether, diethyl ether and cyclohexane) were determined by a shake-flask method. The influence of different factors such as temperature, solvent polarity, mim concentration, and wat...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808030225