Dihydrogen Activation by Lithium‐ and Sodium‐Aluminyls
نویسندگان
چکیده
It turns out there is nothing special about potassium after all: Sodium and lithium metal reduce AlIII iodide precursors to the M2[Al(NONDipp)]2 aluminyls (M=Li, Na). Addition of Et2O afforded monomeric ion pairs (NONDipp)Al-M(Et2O)2 containing unsupported Al−Li Al−Na bonds. All species activate dihydrogen, albeit at significantly different rates reaction.
منابع مشابه
Heterolytic dihydrogen activation by B(C6F5)3 and carbonyl compounds.
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2021
ISSN: ['1521-3773', '1433-7851', '0570-0833']
DOI: https://doi.org/10.1002/anie.202108934