Diffraction studies of aqueous electrolyte solutions

Nuclear magnetic resonance studies of supercooled aqueous electrolyte solutions

The dynamic properties of water molecules coordinated to simple ions (alkali and alkali-earth halides) and hydrophobic ions (tetraalkylammonium (TAA) halides) in supercooled solutions have been investigated with KMR. The study of spin-lattice relaxation rates and self-diffusion coefficients as functions of temperature, pressure, Larmor frequency and concentration reveals characteristic features...

Multicomponent Concentrated Aqueous Electrolyte Solutions

Neutron diffraction studies of water and aqueous solutions under pressure

2014 A summary is given of data obtained from neutron diffraction experiments on heavy water at elevated pressures and temperatures using three different types of pressure vessel. The pressure vessels were manufactured from (i) hard steel (EN24T), (ii) titanium-zirconium null alloy, and (iii) autofrettaged aluminium alloy (7075-T6). In cases (i) and (ii), hydraulic pressures up to 6 kbar were a...

An Evaluation of Four Electrolyte Models for the Prediction of Thermodynamic Properties of Aqueous Electrolyte Solutions

In this work, the performance of four electrolyte models for prediction the osmotic and activity coefficients of different aqueous salt solutions at 298 K, atmospheric pressure and in a wide range of concentrations are evaluated. In two of these models, (electrolyte Non-Random Two-Liquid e-NRTL and Mean Spherical Approximation-Non-Random Two-Liquid MSA-NRTL), association between ions of opposit...

■ The Structure of Aqueous Electrolyte Solutions

This review compares results of neutron and X-ray diffraction experiments with computer simu­ lation and theoretical calculation for aqueous electrolyte solutions at the atomic level in terms of the partial radial distribution functions of several ionic solutions, and includes results for the ion-water and ion-ion structure of systems containing alkali ions, alkaline earth ions, transition meta...