Dichlorido(N,N-diethyl-4-{[(quinolin-2-yl)methylidene]amino-κ2N,N′}aniline)mercury(II)

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Di­chlorido­(N,N-diethyl-4-{[(quinolin-2-yl)methyl­idene]amino-κ2 N,N′}aniline)mercury(II)

In the mononuclear title complex, [HgCl2(C20H21N3)], synthesized from the quinoline-derived Schiff base N (1),N (1)-diethyl-N (4)-(quinolin-2-yl-methyl-idene)benzene-1,4-di-amine (QMBD), the coordination geometry around the Hg(2+) atom is distorted tetra-hedral, comprising two Cl atoms [Hg-Cl = 2.3654 (19) and 2.4394 (18) Å] and two N-atom donors from the QMBD ligand, viz. one imine and quinoli...

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N-(4-Chloro­phen­yl)quinolin-2-amine

There is a twist in the title mol-ecule, C(15)H(11)ClN(2), as seen in the dihedral angle of 18.85 (9)° between the quinoline and benzene rings. A short C-H⋯N contact arises from this conformation and the amine H and quinoline N atoms are directed towards opposite sides of the mol-ecule. In the crystal, supra-molecular layers in the ab plane are mediated by C-H⋯π inter-actions.

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Crystal structure of N 1,N 1-diethyl-N 4-[(quinolin-2-yl)methyl­idene]benzene-1,4-di­amine

The title compound, C20H21N3, is non-planar with a dihedral angle between the planes of the quinoline and phenyl-enedi-amine rings of 9.40 (4)°. In the crystal, mol-ecules are connected by C-H⋯π inter-actions, generating a chain extending along the a-axis direction. Weak C-H⋯π inter-actions also occur.

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4-Chloro-6-methyl-N-(4-methyl­phen­yl)quinolin-2-amine

In the title compound C(17)H(15)ClN(2), the dihedral angle between the quinoline ring system and the phenyl ring is 50.18 (6)°. In the crystal, mol-ecules are linked into chains running along the c axis by N-H⋯N hydrogen bonds.

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[2-Cyclo­propyl-4-(4-fluoro­phenyl)quinolin-3-yl]methanol

The title compound, C(19)H(16)FNO, crystallizes with two independent mol-ecules in the asymmetric unit. In the two mol-ecules, the dihedral angles between the benzene and quinoline rings are 72.6 (5) and 76.2 (5)°, between the cyclo-propane and quinoline rings they are 65.2 (5) and 66.0 (5)°, and between the benzene and cyclo-propane rings they are 25.9 (5) and 33.9 (5)°. There are inter-molecu...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2014

ISSN: 1600-5368

DOI: 10.1107/s160053681400957x