Diamido tantalum(V) complexes derived from a diazamacrocycle
نویسندگان
چکیده
منابع مشابه
Synthesis and characterization of oxorhenium(v) diamido pyridine complexes that catalyze oxygen atom transfer reactions.
The detailed syntheses of complexes 1-4, Re(O)(X)(DAP) (X = Me, 1; Cl, 2; I, 3; OTf (triflate), 4) incorporating the diamido pyridine (DAP) ancillary ligand (2,6-bis((mesitylamino)methyl)pyridine) are described and shown to be effective catalysts for oxygen atom transfer (OAT) reactions of PyO to PPh(3). The catalytic activities are as follows: 4≈3 > 2 > 1. The observed electronic trend is cons...
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ژورنال
عنوان ژورنال: Polyhedron
سال: 2018
ISSN: 0277-5387
DOI: 10.1016/j.poly.2018.04.019