Diallylsilanediol, (CH2=CH-CH2)2-Si(OH)2
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چکیده
منابع مشابه
Probing the barrier for CH2CHCO --> CH2CH + CO by the velocity map imaging method.
This work determines the dissociation barrier height for CH2CHCO --> CH2CH + CO using two-dimensional product velocity map imaging. The CH2CHCO radical is prepared under collision-free conditions from C-Cl bond fission in the photodissociation of acryloyl chloride at 235 nm. The nascent CH2CHCO radicals that do not dissociate to CH2CH + CO, about 73% of all the radicals produced, are detected u...
متن کاملPorphyrins with a carbosilane dendrimer periphery as synthetic components for supramolecular self-assembly.
The preparation of the shape-persistent carbosilane-functionalized porphyrins H2TPP(4-SiRR'Me)4, Zn(II)-TPP(4-SiRR'Me)4 (R = R' = Me, CH2CH=CH2, CH2CH2CH2OH; R = Me, R' = CH2CH=CH2, CH2CH2CH2OH; TPP = tetraphenyl porphyrin), H2TPP(4-Si(C6H4-1,4-SiRR'Me)3)4, and Zn(II)-TPP(4-Si(C6H4-1,4-SiRR'Me)3)4 (R = R' = Me, CH2CH=CH2; R = Me, R' = CH2CH[double bond, length as m-dash]CH2) using the Lindsey c...
متن کاملPhylogenetic Analysis of Beta-Glucanase Producing Actinomycetes Strain TBG-CH22 - A Comparison of Conventional and Molecular Morphometric Approach
Actinomycetes are inexhaustible producers of commercially valuable metabolites, are continually screened for beneficial compounds. The taxonomic and phylogenetic study of novel actinomycetes strains are mostly based on conventional methods and primary DNA structure of 16s rRNA. Although 16s rRNA sequence is well accepted in phylogeny studies, its secondary structures have not been widely used. ...
متن کاملPhylogenetic Analysis of Beta-Glucanase Producing Actinomycetes Strain TBG-CH22 - A Comparison of Conventional and Molecular Morphometric Approach
Actinomycetes are inexhaustible producers of commercially valuable metabolites, are continually screened for beneficial compounds. The taxonomic and phylogenetic study of novel actinomycetes strains are mostly based on conventional methods and primary DNA structure of 16s rRNA. Although 16s rRNA sequence is well accepted in phylogeny studies, its secondary structures have not been widely used. ...
متن کاملReactions of ruthenium hydrides with ethyl-vinyl sulfide.
The Ru-hydride precursors (Im(OMe)2)(PPh3)2RuHCl () and (Me2Im(OMe)2)(PPh3)2RuHCl () reacted with ethyl-vinyl-sulfide to give ((MeOCH2CH2)C3H2N2(CH2CH(OMe))RuCl(PPh3)2 () and ((MeOCH2CH2)C3Me2N2(CH2CH(OMe))RuCl(PPh3)2 (), respectively. Dissolution of () in C6D6 prompts formation of ((MeOCH2CH2)C5H6N2(CHCH)RuCl(PPh3)2 (). The analogous reactions of the bis-carbene Ru-hydride precursors (Im(OMe)2...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1953
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.26.279