DFT study of crystalline nitrosyl compounds
نویسندگان
چکیده
منابع مشابه
Kinetic, mechanistic, and DFT study of the electrophilic reactions of nitrosyl complexes with hydroxide.
We present a kinetic study of OH(-) additions to several nitrosyl complexes containing mainly ruthenium and different coligands (polypyridines, amines, pyridines, cyanides). According to a first-order rate law in each reactant, we propose a fast ion pair formation equilibrium, followed by addition of OH(-) to the [MX(5)NO](n) moieties, with formation of the [MX(5)NO(2)H](n(-1)) intermediates. A...
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ژورنال
عنوان ژورنال: Zeitschrift für Kristallographie - Crystalline Materials
سال: 2008
ISSN: 2196-7105,2194-4946
DOI: 10.1524/zkri.2008.0032