Determination of selenium(IV) and tellurium(IV) by differential-pulse polarography after extraction with ethyl acetate.
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Selective Determination of Trace-Bismuth by Extraction-Differential Pulse Polarography in Non-Aqueous Media
The voltammetric characteristics of bismuth(III)-oxinate in chloroform at the mercury electrode were investigated and a quasi-reversible behavior for Bi(III) oxinate reduction was confirmed. Preceded by the extraction of Bi(III) oxinate in chloroform, differential pulse polarography was developed in the extracts for determination of the trace-bismuth. The linear range of the calibration gra...
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A simple and rapid differential pulse polarographic method was developed for the trace determination of azathioprine. A welldefined polarogram with three peaks was obtained in acetate buffer (pH 5.0) with peak potentials -0.27 V, -0.73 V and -1.02 V. The current-concentration linearity was found extend up to 5 x 10 mol L (r = 0.9992) with minimum detection limit of 2.8x10 mol L. The values of r...
متن کاملIndirect determination of thallium by differential-pulse polarography.
The method is based on the separation of Tl(I) as Tl(2)HPMo(12)O(40), stripping of the molybdate, and measurement of the peak current in differential-pulse polarography of the molybdenum. The calibration graph is linear over the range 2-12 ppm of thallium. The relative standard deviation is 1.2% (7 replicates each containing 500 microg of thallium). The current due to reduction of the molybdenu...
متن کاملPreconcentration of bismuth(III) and copper(II) by solid-phase extraction and subsequent determination by differential pulse polarography.
A differential pulse polarographic method is proposed for the trace determination of bismuth and copper from large volumes of aqueous samples after adsorption of their 1-(2-thiazolylazo)-2-naphthol complexes onto microcrystalline naphthalene in the pH ranges of 7.2-9.0 and 4.0-7.8, respectively. Bismuth and copper are desorbed from microcrystalline naphthalene with 9 mL 1M HCl. Well-defined pea...
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A highly selective, rapid and economical differential pulse polarographic method has been developed for the determination of trace amounts of cadmium and lead present together in various standard alloys and biological samples after adsorption of their 1-(2-pyridylazo)-2-naphthol complexes on microcrystalline naphthalene. Cadmium and lead complexes are equantitatively adsorbed on microcrysta...
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ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 1987
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.36.11_735