Determination of Fluorine and Chlorine in Organic Compounds

Determination of fluorine in organic compounds.

synthesis of 3-aryl-2h-benzo[b]-1,4-oxazines in [omim]bf4 and reduction of organic compounds in methylimidazolium formate

در این پروژه ترکیبات 3-آریل-2h-بنزو[b]-4،1-اکسازین ها از مواد اولیه تجاری مشتقات دو آمینو فنول و ?-هالو کتون های آروماتیک در مایع یونی 1-اکتیل-3-متیل ایمیدازولیوم تترا فلورو بورات([omim]bf4) سنتز شده است. این واکنش توسط باز پتاسیم کربنات محلول از طریق o-آلکیلاسیون و سپس یک واکنش آمیداسیون درون مولکولی خود بخود در مدت زمان کوتاه انجام می شود. ترکیبات 4،1-بنزوکسازین به این روش با بهره خوب تا آلی ...

Determination of chlorine in organic compounds containing mercury

The standard procedure for the determination of chlorine in organic compounds of mercury consists in decomposition of the material, separation of mercury and determination of chlorine as chloride. Decomposition of the sample could be achieved by wet mineralization [1,2], ignition in a stream of oxygen [3—7] or nitrogen [8], ignition in a flask with oxygen [9], etc. [10, 11]. Chlorine and mercur...

Thermochemistry of Organic Fluorine Compounds and Carbon Compounds

Rotating-bomb calorimetry was first applied to organic compounds that contain chlorine, bromine, or sulphur. Techniques developed for these classes of compounds, mostly at the University of Lund and at the Bureau of Mines in Bartlesville, have been described in the book Experimental Thermochemistry-, The development of rotating-bomb methods made accurate combustion calorimetry feasible for othe...

Potentiometric Determination of Acidity Constants of Some Synthesized Organic Compounds in Organic-Water Media

The acidity constants of some synthesized protonated pyrazolo quinazoline compounds were determined potentiometrically at ionic strength of 0.1 M in DMF: water (60:40 v/v) system at different temperatures (298.15 K to 318.15 K). The pKa values have been found to increase with increasing electron-donating nature of substitutions. Some thermodynamics parameters such as enthalpy (ΔH°), Gibb’s free...