Defects and Persistent Luminescence in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline" overflow="scroll"><mml:mi>Eu</mml:mi></mml:math> -Doped <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline" overflow="scroll"><mml:mrow><mml:mi>Sr</mml:mi><mml:mi>Al</mml:mi></mml:mrow></mml:math> <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline" overflow="scroll"><mml:msub><mml:mi /><mml:mn>2</mml:mn></mml:msub></mml:math> <mml:math …
نویسندگان
چکیده
We investigate native point defects and rare-earth (co)dopants in SrAl$_2$O$_4$ using hybrid density-functional defect calculations. Europium (Eu) dysprosium (Dy) are found to be mixed valence energetically most favorable at the Sr lattice sites. However, unlike Eu where both Eu$^{2+}$ Eu$^{3+}$ can realized synthesis, Dy is stable predominantly as Dy$^{3+}$, divalent Dy$^{2+}$ may only photogenerated under irradiation. On basis of an analysis Eu-related band-defect (including charge-transfer) interconfigurational $5d$-$4f$ optical transitions, we assign characteristic broad blue (445 nm) green (520 emission bands Eu$^{2+}$-doped $4f^65d^1$ $\rightarrow$ $4f^7$ transition incorporated Sr1 Sr2 sites, respectively. Strontium interstitials (not oxygen vacancies, contrast what commonly believed) Dy$_{\rm Sr}$ act efficient electron traps for room-temperature persistent luminescence. This work calls a re-assessment certain assumptions regarding specific carrier trapping centers made all mechanisms previously proposed luminescence Eu- (Eu,Dy)-doped SrAl$_2$O$_4$. It also serves methodological template understanding design doped phosphors.
منابع مشابه
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ژورنال
عنوان ژورنال: Physical review applied
سال: 2023
ISSN: ['2331-7043', '2331-7019']
DOI: https://doi.org/10.1103/physrevapplied.19.024060