Cycloaddition of tert-butylcyanoketene to isocyanides
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چکیده
منابع مشابه
Cycloaddition of Diphenylnitrilimine to 1,5-Benzodiazepines
The cycloaddition reaction of diphenylnitrilimine on the 1,5-benzodiazepines has been studied. New molecules of triazolobenzodiazepines type have been isolated and characterized.
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Despite the long history of the investigation of nucleophilic addition to metal-bound isocyanides, some important aspects of the reaction mechanism remain unclear even for the simplest systems. In this work, the addition of the sp³-N, sp²-N, and mixed sp²/sp³-N nucleophiles (i.e., HNMe₂, HN=CPh₂, and H₂N-N=CPh₂, respectively) to isocyanides C≡NR coordinated to the platinum(II) centers in the co...
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ژورنال
عنوان ژورنال: The Journal of Organic Chemistry
سال: 1981
ISSN: 0022-3263,1520-6904
DOI: 10.1021/jo00337a023