Cyclization of Isomeric 2-Hydrazino-4-methylbenzo[h]quinoline and 3-Hydrazino-1-methylbenzo[f]quinoline. A Reinterpretation
نویسندگان
چکیده
منابع مشابه
4-Hydrazino-2-(methylsulfanyl)pyrimidine
In the crystal of the title compound, C(5)H(8)N(4), centrosymmetric dimers are linked by pairs of N-H⋯N hydrogen bonds. Further N-H⋯N links result in a two-dimensional array whereby wave-like supra-molecular chains are inter-connected by R(2) (2)(8) ring motifs.
متن کامل4-Hydrazino-1-methylpyrazolo[3,4-d]pyrimidine
The title compound, C(6)H(8)N(6), crystallizes as an N-H⋯N hydrogen-bond-linked dimer of two almost identical mol-ecules in the asymmetric unit. Both of the mol-ecules are almost planar (rms deviations of 0.0186 and 0.0296 Å in the two molecules) and their hydrazino groups are turned towards the pyrazole rings. The dimers are arranged into chains via inter-molecular N-H⋯N hydrogen bonds between...
متن کامل4-[2-(1-Acetyl-2-oxopropylidene)hydrazino]-N-(pyrimidin-2-yl)benzenesulfonamide
In the title compound, C(15)H(15)N(5)O(4)S, the dihedral angle between the pyrimidine and benzene rings is 84.56 (2)°. Intra-molecular hydrazine-carbonyl N-H⋯O and inter-molecular sulfonamide-pyridimine N-H⋯N hydrogen bonds stabilize the mol-ecular and crystal structures, respectively.
متن کامل3-(1,3-Dioxolan-2-yl)-2-hydrazino-7-methylquinoline
In the title mol-ecule, C(13)H(15)N(3)O(2), the dihedral angle between the mean plane of the 1,3-dioxolane group and the 2-hydrazino-7-methyl-isoquinoline unit is 85.21 (5)°. The conformation of the mol-ecule is influenced by bifurcated N-H⋯(O,O) and N-H⋯N intra-molecular hydrogen bonds. In the crystal structure, mol-ecules are linked via inter-molecular N-H⋯O hydrogen bonds, forming extended c...
متن کامل3-Nitro, 1-Amino Guanidine and 5-Hydrazino-1H-Tetrazole Derivatives as New Energetic Materials
The synthesis of 3-amino-1-nitroguanidine (3-ANQ) and 5-hydrazino tetrazole (5-HT) derivatives as new energetic materials are described. Reaction of 3-ANQ with triethyl orthoformate leads to the formation of 3-nitramino triazole while no reaction was observed whit 5-HT. Addition of NaN3 to a mixture of 3-ANQ and triethyl orthoformate, afforded 1-nitroguanidyl tetrazole in excelle...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1982
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.55.349