Crystal structures of cis- and trans-2-azido-indan-1-ol, C9H9N3O
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چکیده
منابع مشابه
Enantioselective Desymmetrization of Glutarimides Catalyzed by Oxazaborolidines Derived from cis-1-Amino-indan-2-ol.
Enantioselective reductive desymmetrization of glutarimides has been achieved employing an oxazaborolidine catalyst derived from cis-1-amino-indan-2-ol. The reaction was found to proceed through a stereoablative process that upgraded the enantioselectivity of an intermediate hydroxy-lactam. The reaction was generally tolerant of a number of substituents in the 4-position, giving enantiomeric ex...
متن کاملpreparation of epoxy alcohols from cis and trans 2-(1-cyclohexenyl cyclohexanol and 2-cyclohexylidene cyclohexanone
epoxyalcohols are useful intermediates in complex organic synthesis, and recently they have been recognized as versatile intermediates for synthesis of natural products. the treatments of cis and trans 2-(1-cyclohexenyl) cyclohexanol, separately with paranirto perbenzoic acid gave the corresponding 2-(1- cyclohexenyl) cyclohexanol oxide. on the other hand, 2-cyclohexylidene cyclohexanol oxide w...
متن کامل(1S,2R)-1-[(E)-(Thiophen-2-ylmethylidene)amino]indan-2-ol
In the title compound, C(14)H(13)NOS, the dihedral angle formed by the mean planes through the indane ring system and the thio-phene ring is 85.04 (11)°. The imine bond is located in the thio-phene plane [the S-C-C-N torsion angle is 0.00 (3)°] and an intra-molecular O-H⋯N hydrogen bond is observed.
متن کاملTheoretical study of cis and trans structures
The large number of compounds that may exhibit cis-trans isomerism in inorganic chemistry illustrates, in terms of number of known examples, the progress of synthetic inorganic chemistry. In fact, from the studies conducted by Werner at the beginning of this century to the present day, a huge range of works involving this type of isomers can be found in the literature. 1-7 In the case of isomer...
متن کاملcis-2-(4-Methoxyphenyl)-4-methyl-1,2-dihydronaphthalen-1-ol
The stereochemistry and regiochemistry of the title compound, C18H18O2, were determined by the X-ray analysis. There are two independent mol-ecules in the asymmetric unit in which the dihedral angles between the benzene rings are 88.31 (4) and 86.27 (4)°. The cyclo-hexene rings are in half-chair conformations. In the crystal, O-H⋯O hydrogen bonds link alternating types of mol-ecules into chains...
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ژورنال
عنوان ژورنال: Zeitschrift für Kristallographie - New Crystal Structures
سال: 2000
ISSN: 2197-4578,1433-7266
DOI: 10.1515/ncrs-2000-0473