Crystal structures and Hirshfeld surface analyses of (N-hexyl-N-methyldithiocarbamato-κ2 S,S′)triphenyltin(IV) and [N-methyl-N-(2-phenylethyl)dithiocarbamato-κ2 S,S′]triphenyltin(IV)
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Di-n-butylbis[N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]tin(IV): crystal structure and Hirshfeld surface analysis
The complete mol-ecule of the title compound, [Sn(C4H9)2(C5H10NOS2)2], is generated by a crystallographic mirror plane, with the SnIV atom and the two inner methyl-ene C atoms of the butyl ligands lying on the mirror plane; statistical disorder is noted in the two terminal ethyl groups, which deviate from mirror symmetry. The di-thio-carbamate ligand coordinates to the metal atom in an asymmetr...
متن کاملCrystal structures of (2,2′-bipyridyl-κ2 N,N′)bis[N,N-bis(2-hydroxyethyl)dithiocarbamato-κ2 S,S′]zinc dihydrate and (2,2′-bipyridyl-κ2 N,N′)bis[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ2 S,S′]zinc
The common feature of the title compounds, [Zn(C5H10NO2S2)2(C10H8N2)]·2H2O, (I), and [Zn(C6H12NOS2)2(C10H8N2)], (II), is the location of the Zn(II) atoms on a twofold rotation axis. Further, each Zn(II) atom is chelated by two symmetry-equivalent and symmetrically coordinating di-thio-carbamate ligands and a 2,2'-bi-pyridine ligand. The resulting N2S4 coordination geometry is based on a highly ...
متن کاملBis(μ2-N-methyl-N-phenyldithiocarbamato)-κ3 S,S′:S;κ3 S:S,S′-bis[(N-methyl-N-phenyldithiocarbamato-κ2 S,S′)cadmium]: crystal structure and Hirshfeld surface analysis
The title compound, [Cd2(C8H8NS2)4], is a centrosymmetric dimer with both chelating and μ2-tridentate di-thio-carbamate ligands. The resulting S5 donor set defines a CdII coordination geometry inter-mediate between square-pyramidal and trigonal-bipyramidal, but tending towards the former. The packing features C-H⋯S and C-H⋯π inter-actions, which generate a three-dimensional network. The influen...
متن کامل[N-Benzyl-N-(2-phenylethyl)dithiocarbamato-κ2 S,S′]triphenyltin(IV) and [bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]triphenyltin(IV): crystal structures and Hirshfeld surface analysis
The crystal and mol-ecular structures of two tri-phenyl-tin di-thio-carbamates, [Sn(C6H5)3(C16H16NS2)], (I), and [Sn(C6H5)3(C7H14NO2S2)], (II), are described. In (I), the di-thio-carbamate ligand coordinates the SnIV atom in an asymmetric manner, leading to a highly distorted trigonal-bipyramidal coordination geometry defined by a C3S2 donor set with the weakly bound S atom approximately trans ...
متن کاملDistinct coordination geometries in bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]diphenyltin(IV) and bis[N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]diphenyltin(IV): crystal structures and Hirshfeld surface analysis
The crystal and mol-ecular structures of two di-phenyl-tin bis-(di-thio-carbamate)s, [Sn(C6H5)2(C5H10NOS2)2], (I), and [Sn(C6H5)2(C7H14NO2S2)2], (II), are described. In (I), in which the metal atom lies on a twofold rotation axis, the di-thio-carbamate ligand coordinates with approximately equal Sn-S bond lengths and the ipso-C atoms of the Sn-bound phenyl groups occupy cis-positions in the res...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Crystallographic Communications
سال: 2018
ISSN: 2056-9890
DOI: 10.1107/s2056989018005133