Crystal structure of tris[μ2-bis(diphenylphosphanyl)methane-κ2P:P′]di-μ3-iodido-trisilver(I) iodide–N-phenylthiourea (1/1)
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چکیده
منابع مشابه
Bis(tetrapropylammonium) di-μ3-iodido-di-μ2-iodido-diiodidodipyridinetetracopper(I)
The title compound, (C(12)H(28)N)(2)[Cu(3.194)I(6)(C(5)H(5)N)(2)] was prepared from reaction of copper powder, copper(I) oxide, hydro-iodic acid, tetra-propyl-ammonium iodide and pyridine under hydro-thermal conditions. In the centrosymmetric Cu(4)I(6) (2-) anion, one Cu site is in a trigonal-planar coordination while the second Cu site, which is only partially occupied [site occupancy of 0.596...
متن کاملCrystal structure of tris[μ2-bis(diphenylphosphanyl)methane-κ2 P:P′]di-μ3-iodido-trisilver(I) iodide–N-phenylthiourea (1/1)
The title complex, [Ag3I2(C25H22P2)3]I·C7H8N2S, comprises a trinuclear [Ag3I2(C25H22P2)3](+) unit, an I(-) anion and one N,N'-phenyl-thio-urea mol-ecule (ptu). Two μ3-bridging I(-) anions are linked by three Ag(I) ions, leading to the formation of a dicapped triangular motif with Ag⋯Ag separations in the range 3.0823 (5)-3.2999 (5) Å. Each Ag(I) atom exhibits a distorted tetra-hedral geometry, ...
متن کاملTetra-μ3-iodido-tetrakis[(tri-n-butylphosphane-κP)copper(I)]
The title complex, [Cu4I4(C12H27P)4], crystallizes with six mol-ecules in the unit cell and with three independent one-third mol-ecule fragments, completed by application of the relevant symmetry operators, in the asymmetric unit. The tetranuclear copper core shows a tetrahedral geometry (site symmetry 3..). The I atoms also form a tetra-hedron, with I⋯I distances of 4.471 (1) Å. Both tetra-hed...
متن کاملBis(μ-di-2-pyridyl disulfide-κ3 N,S:N′)di-μ3-iodido-di-μ2-iodido-tetracopper(I)
In the centrosymmetric tetra-nuclear title compound, [Cu(4)I(4)(C(10)H(8)N(2)S(2))(2)], there are two different Cu(I) atoms with tetra-hedral coordination geometries. One is chelated by a pyridine N atom and an S-donor from one di-2-pyridyl disulfide ligand and coordinated by two I atoms, while the second Cu(I) atom is coordinated by a pyridine-N and three I atoms. Iodine bridges between the Cu...
متن کاملCrystal structure of di-μ-iodido-bis[bis(acetonitrile-κN)copper(I)]
The title compound, [Cu2I2(CH3CN)4], exhibits a centrosymmetric Cu2I2 core [Cu⋯Cu distance = 2.7482 (11) Å], the Cu(I) atoms of which are further coordinated by four mol-ecules of aceto-nitrile. The Cu(I) atom has an overall distorted tetra-hedral coordination environment evidenced by L-Cu-L angles (L = N or I) ranging from 100.47 (10) to 117.06 (2)°. The coordination geometries of the aceto-ni...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Crystallographic Communications
سال: 2015
ISSN: 2056-9890
DOI: 10.1107/s2056989015017120