Crystal structure of poly[deca aqua-bis(<i>μ</i> <sub>4</sub>-2-(triazol-1-yl)-benzene-1,3,5-tricarboxylato)- bis(<i>μ</i> <sub>5</sub>-2-(triazol-1-yl)-benzene-1,3-dicarboxylato-5-carboxyl acid) pentamanganese(II)] dihydrate, C<sub>44</sub>H<sub>42</sub>Mn<sub>5</sub>N<sub>12</sub>O<sub>36</sub>
نویسندگان
چکیده
Abstract C 44 H 42 Mn 5 N 12 O 36 , triclinic, P 1 ‾ $\overline{1}$ (no. 2), a = 7.6398(7) Å, b 9.9043(5) c 20.1160(13) α 87.300(5)°, β 81.868(6)°, γ 67.555(7)°, V 1392.62(18) Å 3 Z 1, R gt ( F ) 0.0554, w ref 2 0.1446, T 293(2) K.
منابع مشابه
Benzene-1,3,5-tricarboxylic acid–1,10-bis(1,2,4-triazol-1-yl)decane–water (1/1/2)
In the title 1:1:2 association, C(14)H(24)N(6)·C(9)H(6)O(6)·2H(2)O, the alkyl chain in the 1,10-bis-(1,2,4-triazol-1-yl)decane mol-ecule adopts an extended conformation and the dihedral angle between the aromatic rings is 10.28 (13)°. The benzene-1,3,5-tricarb-oxy-lic acid mol-ecule is close to being planar (r.m.s. deviation = 0.052 Å). In the crystal, the components are linked by O-H⋯O and O-H...
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The asymmetric unit of the title compound, C(10)H(8)N(6)·2H(2)O, comprises half the organic species, the mol-ecule being completed by inversion symmetry, and one water mol-ecule. The dihedral angle between the 1,2,4-triazole ring and the central benzene ring is 32.2 (2)°. The water mol-ecules form O-H⋯N hydrogen bonds with N-atom acceptors of the triazole rings. C-H⋯N hydrogen bonds are also ob...
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The title compound, 4C(9)H(6)O(6)·C(6)H(8)N(6)·2H(2)O, crystallizes in a layer structure where each sheet is composed of anellated hydrogen-bonded rings of six distinct sizes: R(2) (2)(16), R(3) (3)(18), R(4) (4)(12), R(4) (4)(18), R(4) (4)(22) and R(4) (4)(25). The two largest rings, viz. R(4) (4)(22) and R(4) (4)(25), are associated with O-H⋯N bonds from the carboxyl groups to the triazole ri...
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In the title compound, C(9)H(9)ClN(4)OS, the two rings enclose a dihedral angle of 84.67 (11)°. Inter-molecular C-H⋯O and C-H⋯N hydrogen bonds stabilize the crystal packing.
متن کامل2-Amino-4-[1-(2-chlorophenyl)-5-methyl-1H-1,2,3-triazol-4-yl]-6-(4-methylphenyl)benzene-1,3-dicarbonitrile
In the title compound, C(24)H(17)ClN(6), the dihedral angles between the triazolyl ring and its adjacent chlorobenzene and trisubstituted benzene rings are 90.6 (2) and 55.7 (3)°, respectively. The dihedral angle between the trisubstituted ring and the attached tolyl ring of the biphenyl unit is 45.9 (3)°. Intra- and intermolecular N-H⋯N hydrogen bonds are present.
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ژورنال
عنوان ژورنال: Zeitschrift Fur Kristallographie-new Crystal Structures
سال: 2022
ISSN: ['2197-4578', '1433-7266']
DOI: https://doi.org/10.1515/ncrs-2022-0136