Crystal structure of (μ-oxo)-tris(μ-isopropoxy)-pentakis(isopropoxy)- tris(phenylphosphonato)-tetrahydrofuran-tetratitanium tetrahydrofuran solvate, [Ti4(μ3-O)(μ-OiPr)3(OiPr)5(PhPO3)3(THF)] · 1/2 THF

Iodide solvation in tetrahydrofuran clusters: I(THF)

(Tetrahydrofuran)potassium mer-trans-tris(carbazolyl)dichloro(tetrahydrofuran)zirconate.

In the title compound, [K(C(4)H(8)O)][ZrCl(2)(C(12)H(8)N)(3)(C(4)H(8)O)], the Zr atom is pseudo-octahedral, with two Cl ligands in trans positions. There is extensive interaction between the potassium cation and two of the aromatic carbazolyl ligands in eta(6) [C.K = 3.167 (3)-3.331 (3) A] and eta(2) [C.K = 3.147 (3)-3.268 (2) A] fashions.

The Role of Solvent Structure in the Absorption Spectrum of Solvated Electrons: Mixed Quantum/Classical Simulations in Tetrahydrofuran (THF)

In polar fluids such as water and methanol, the peak of the solvated electron’s absorption spectrum in the red has been assigned as a sum of transitions between an s-like ground state and three nearly degenerate p-like excited states bound in a quasi-spherical cavity. In contrast, in weakly polar solvents such as tetrahydrofuran (THF), the solvated electron has an absorption spectrum that peaks...

Trehalose promotes Rhodococcus sp. strain YYL colonization in activated sludge under tetrahydrofuran (THF) stress

Few studies have focused on the role of compatible solutes in changing the microbial community structure in bioaugmentation systems. In this study, we investigated the influence of trehalose as a biostimulant on the microbial community in tetrahydrofuran (THF)-treated wastewater bioaugmentation systems with Rhodococcus sp. YYL. Functional gene profile changes were used to study the variation in...

Watching Na atoms solvate into (Na+,e-) contact pairs: untangling the ultrafast charge-transfer-to-solvent dynamics of Na- in tetrahydrofuran (THF).

With the large dye molecules employed in typical studies of solvation dynamics, it is often difficult to separate the intramolecular relaxation of the dye from the relaxation associated with dynamic solvation. One way to avoid this difficulty is to study solvation dynamics using an atom as the solvation probe; because atoms have only electronic degrees of freedom, all of the observed spectrosco...