Crystal structure of dicaesium hexachlorotungstate(IV), Cs2[WCl6]
نویسندگان
چکیده
منابع مشابه
Dicaesium hexamercury heptasulfide
The title compound, Cs(2)Hg(6)S(7), crystallizes in a new structure type that is closely related to that of K(2)Zn(6)O(7). The structure comprises a three-dimensional mercury sulfide network that is composed of channels. These channels, which are along [001], are of two different diameters. The crystal structure contains one Cs, two Hg, and three S atoms in the asymmetric unit. The Cs, one Hg, ...
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The asymmetric unit of the title compound, [Cs(2)(C(2)N(10))](n), comprises a Cs(+) cation, and one-half of a 5,5'-diazenediylditetra-zolide anion. The Cs(+) cation is six-coordinated by N atoms from six 5,5'-diazenediylditetra-zolide ligands. Each 5,5'-diazenediylditetra-zolide ligand is surrounded by 12 Cs(+) cations, coordinating through ten N atoms. The Cs(+) cations are arranged in a chain...
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The reaction of [PPhJ, NOS,] with CuCl and KSCN (1 :3:3) in acetone produces the yell-ow crystals of [PPh,], [WOS,(CuNCS),]. The crystals are triclinic, space group P1(2), z=2, a=12.4823(7), b=12.9224(7), c=18.6395(10)?, ?=83.907(5), ?= 73.152(4), Y= 65.194(4)'. The crystal structure was determined by single crystal Xray diffraction methods (Mo-K ?) and refined by least-squares calculations ...
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The anion of the title complex, Cs(2)[PuCl(4)O(2)], adopts a pseudo-octa-hedral geometry (2/m crystallographic site symmetry) with two plutonyl oxide ligands in axial sites and four chloride ligands occupying the equatorial plane. Charge balance is maintained by two caesium cations per tetra-chlorido-dioxido-plutonate(VI) anion. Principal bond lengths include Pu-O = 1.752 (3) Å and Pu-Cl = 2.66...
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The structure of the nonaaquayttrium (III) bromate, [Y(H2O)9](BrO3)3, at low temperature (100 K) has been studied by means of single-crystal X-ray diffraction. Crystallography shows a hexagonal unit cell, space group P63/mmc (No. 194) with Z = 2, a = b = 11.7104(11) Å, c = 6.6259(5) Å and V = 786.90(12) Å3 at 100 K. The hydra...
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ژورنال
عنوان ژورنال: Zeitschrift für Kristallographie - New Crystal Structures
سال: 2003
ISSN: 2197-4578,1433-7266
DOI: 10.1524/ncrs.2003.218.1.25