Crystal structure of dibromo-bis(1,3-imidazolidine-2-thione-S)zinc(II), ZnBr2 (C3H6N2S)2

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Penta­carbon­yl(imidazolidine-2-thione-κS)tungsten(0)

In the title complex, [W(C(3)H(6)N(2)S)(CO)(5)], the W atom displays an octa-hedral coordination with five CO mol-ecules and an imidazolidine-2-thione mol-ecule. The W(CO)(5) unit is coordinated by the cyclic thione ligand through a W-S dative bond. The W-S and C-S bond lengths are 2.599 (2) and 1.711 (9) Å, respectively. This last distance is significantly longer than that of free cyclic thio-...

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The complete molecule of the title compound, C(19)H(22)N(2)S, is generated by crystallographic twofold symmetry with the C=S group lying on the rotation axis. The imidazolidine ring adopts a flattened twist conformation. The dihedral angle between the asymmetric part of the imidazolidine-2-thione fragment and the benzene ring is 89.49 (17)°.

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1,3-Bis(1-cyclo­hexyl­eth­yl)imidazolidine-2-thione

The complete mol-ecule of the title compound, C(19)H(34)N(2)S, is generated by crystallographic twofold symmetry, with the C=S group lying on the rotation axis. A short C-H⋯S contact occurs in the mol-ecule. The five-membered ring is twisted and the cyclo-hexyl ring adopts a chair conformation. The dihedral angle between the mean plane of the five-membered ring and the basal plane of the cyclo-...

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In the title mol-ecule, C(15)H(17)N(3)O(2)S(2), the dihedral angle between the naphthalene ring system and the imidazole ring is 89.63 (2)°. The crystal structure is stablized by weak inter-molecuar C-H⋯π and N-H⋯π inter-actions.

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ژورنال

عنوان ژورنال: Zeitschrift für Kristallographie - New Crystal Structures

سال: 2006

ISSN: 2197-4578,1433-7266

DOI: 10.1524/ncrs.2006.221.14.221