Crystal structure of anion exchangeable Mg2+-Al3+layered double hydroxides
نویسندگان
چکیده
منابع مشابه
Observation of cation ordering and anion-mediated structure selection among the layered double hydroxides of Cu(II) and Cr(III).
Highly ordered Cl(-) and SO4(2-)-intercalated layered double hydroxides (LDHs) of Cu(II) and Cr(III) are obtained when coprecipitation is carried out at low pH ~ 5 and elevated temperature (60-80 °C). Precipitation under other conditions results in the formation of a gel. The SO4(2-)-LDH exhibits weak reflections which could be indexed to the 100 and 101 planes of a supercell corresponding to a...
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متن کاملANION EXCHANGE REACTIONS OF LAYERED DOUBLE HYDROXIDES (LDHs) AND LAYERED HYDROXY SALTS (LHSs): QUANTIFICATION OF ION EXCHANGE Abstract Anion exchange reactions of a number of layered double hydroxides with inorganic anions
Anion exchange reactions of a number of layered double hydroxides with inorganic anions were investigated. The five LDH systems used in this study were Mg-Al, Ni-Al, Co-Al, Zn-Al and Zn-Cr. Ni-Zn hydroxynitrate and Ni-Zn hydroxyacetate were the LHSs used in this work. In general, all the LDHs and nickel zinc hydroxysalts exhibited higher extent of exchange towards chloride ions. The extent of e...
متن کاملThe importance of proper crystal-chemical and geometrical reasoning demonstrated using layered single and double hydroxides
Atomistic modelling techniques and Rietveld refinement of X-ray powder diffraction data are widely used but often result in crystal structures that are not realistic, presumably because the authors neglect to check the crystal-chemical plausibility of their structure. The purpose of this paper is to reinforce the importance and utility of proper crystal-chemical and geometrical reasoning in str...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography
سال: 2011
ISSN: 0108-7673
DOI: 10.1107/s0108767311081803