Crystal structure, Magnetic and Photoluminescence Properties of GdW 6 Cl 15 , TbW 6 Cl 15 , and EuW 6 Cl 14
نویسندگان
چکیده
منابع مشابه
Redetermination of [EuCl2(H2O)6]Cl
The crystal structure of the title compound, hexa-aqua-dichlorido-europium(III) chloride, was redetermined with modern crystallographic methods. In comparison with the previous study [Lepert et al. (1983 ▶). Aust. J. Chem. 36, 477-482], it could be shown that the atomic coordinates of some O atoms had been confused and now were corrected. Moreover, it was possible to freely refine the positions...
متن کاملSynthesis, Characterization, and Crystal Structure Determination of Iron(III) Hetero-ligand Complex Containing Chloride, Dimethyl sulfoxide, pyridine-2, 6-dicarboxylate and Water, [Fe(Pydc)(DMSO)(H2O)Cl]
A new metal-organic compound, [Fe(Pydc)(DMSO)(H2O)Cl], (where Pydc is pyridine-2, 6-dicarboxylate and DMSO is dimethyl sulfoxide), has been synthesized and characterized by singlecrystal X-ray diffraction, TGA/DTA, IR and Raman spectroscopy. Green-yellow crystals,crystallized in the monoclinic system, space group P21/n, a = 7.2461(4) Å, b = 10.3018(4) Å, c =17.7667(10) Å, α = 90°, β = 90.014°(5...
متن کاملSynthesis, crystal structure and magnetic properties of H2tppz[ReCl6] and [Cu(bpzm)2(μ-Cl)ReCl3(μ-ox)Cu(bpzm)2(μ-ox)ReCl3(μ-Cl)]n.
Two new Re(iv) compounds of formulae H2tppz[ReCl6] (1) and [Cu(bpzm)2(μ-Cl)ReCl3(μ-ox)Cu(bpzm)2(μ-ox)ReCl3(μ-Cl)]n (2) [tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine and bpzm = bis(pyrazolyl-1-yl)methane] have been prepared and their crystal structures determined by X-ray diffraction on single crystals. Compound 1 is a mononuclear species whose structure consists of octahedral hexachlororhenate(iv...
متن کاملcatena-Poly[copper(II)-bis(μ-2,4-dichloro-6-formylphenolato)-κ3 O,O′:Cl 4;κ3 Cl 4:O,O′]
In the title compound, [Cu(C(7)H(3)Cl(2)O(2))(2)](n), the Cu(II) atom lies on a centre of inversion and adopts a [4+2] coordination mode, with two long axial Cu-Cl coordinative bonds complementing four Cu-O bonds from two 2,4-dichloro-6-formyl-phenolate ligands in a distorted square plane. π-π stacking inter-actions are also formed between neighbouring aromatic rings, with a centroid-centroid s...
متن کاملsynthesis, characterization, and crystal structure determination of iron(iii) hetero-ligand complex containing chloride, dimethyl sulfoxide, pyridine-2, 6-dicarboxylate and water, [fe(pydc)(dmso)(h2o)cl]
a new metal-organic compound, [fe(pydc)(dmso)(h2o)cl], (where pydc is pyridine-2, 6-dicarboxylate and dmso is dimethyl sulfoxide), has been synthesized and characterized by singlecrystal x-ray diffraction, tga/dta, ir and raman spectroscopy. green-yellow crystals,crystallized in the monoclinic system, space group p21/n, a = 7.2461(4) å, b = 10.3018(4) å, c =17.7667(10) å, α = 90°, β = 90.014°(5...
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ژورنال
عنوان ژورنال: Zeitschrift für anorganische und allgemeine Chemie
سال: 2021
ISSN: 0044-2313,1521-3749
DOI: 10.1002/zaac.202100046