Correlation of closed-cup flash points with normal boiling points for silicone and general organic compounds
نویسندگان
چکیده
منابع مشابه
Normal Boiling Points for Organic Compounds: Correlation and Prediction by a Quantitative Structure-Property Relationship
We recently reported a successful correlation of the normal boiling points of 298 organic compounds containing O, N, Cl, and Br with two molecular descriptors.1 In the present study the applicability of these two descriptors for the prediction of boiling points for various other classes of organic compounds was investigated further by employing a diverse data set of 612 organic compounds contai...
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The boiling points, rates of change of boiling point with pressure, and densities of methyl acetate, ethyl acetate, n-propyl acetate, and n-butyl acetate were measured by precise comparative methods using water as the reference standard . As in previous work on the normal saturated hydrocarbons and normal aliphatic alcohols, it was found that the introduction of each CH2 group into the chain of...
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A quantitative structure property relationship study of the flash point of a diverse set of 271 compounds provided a general three-parameter QSPR model (R(2) = 0.9020, R(2)(cv) = 0.8985, s = 16.1). Use of the experimental boiling point as a descriptor gives a three-descriptor equation with R(2) = 0.9529. Use of the boiling point predicted by a four-parameter reported relationship gives a three-...
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ژورنال
عنوان ژورنال: Fire and Materials
سال: 1997
ISSN: 0308-0501,1099-1018
DOI: 10.1002/(sici)1099-1018(199711/12)21:6<277::aid-fam617>3.0.co;2-3