Conversion of sugars to methyl lactate with exfoliated layered stannosilicate UZAR-S4

نویسندگان

چکیده

• Exfoliation of layered stannosilicate greatly increases its catalytic performance. In sucrose conversion, the exfoliated catalyst shows a methyl lactate yield approximately 50 %. Exfoliated is active after several reaction cycles. Biomass has been shown as an alternative to fossil fuels for obtaining chemicals. this work, transformation sugars into (ML) at 160 °C was carried out using UZAR-S3 (University Zaragoza-solid number 3) and delaminated material UZAR-S4 4) obtained from exfoliation. The exfoliation increased accessibility compounds sites medium-strength acidity. Thus, ML 8% 49.9 % UZAR-S4. reusability tests, characterized before by techniques such X-ray diffraction, thermogravimetry analysis, scanning electronic microscopy, energy dispersive spectroscopy nitrogen adsorption. A deactivation observed, which related carbonaceous deposits that decreased specific surface area pore volume catalyst.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Development of Exfoliated Layered Stanosilicate for Hydrogen Adsorption

The use of hydrogen as an energy vector involves among other steps storage. This has caused the development of new materials with high hydrogen adsorption capacity. In this field, new layered stannosilicate, called UZAR-S3, has been synthesized and delaminated becoming UZAR-S4. The new materials have been characterized by several techniques: XRD, XRF, SEM, TEM, TGA, adsorption of N2, H2 and CO2...

متن کامل

The Synthesis of an Interstratified Layered Oxide from Exfoliated Precursors

Aqueous suspensions of exfoliated Li0 .25MoO 3 and Na-montmorillonite have been combined and dried to form interstratified solids. X-ray diffraction patterns of ethylene glycol treated films show that the d-spacing of restacked materials varies with composition between the limits established by the two end members. Based on these data, we conclude that the new materials are composed of individu...

متن کامل

Determination of reducing sugars with 3-methyl-2-benzothiazolinonehydrazone.

M. (1992) Purification and characterization of human salivarygland prokallikrein from recombinant baculovirus-infected insect cells. Eur. J. Biochem. 206, 225–233. 6. Takada, Y., Skidgel, R. A., and Erdös, E. G. (1985) Purification of human urinary prokallikrein. Biochem. J. 232, 851–858. 7. Noda, Y., Takada, Y., and Erdös, E. G. (1985) Activation of human and rabbit prokallikrein by serine and...

متن کامل

a comparison of teachers and supervisors, with respect to teacher efficacy and reflection

supervisors play an undeniable role in training teachers, before starting their professional experience by preparing them, at the initial years of their teaching by checking their work within the proper framework, and later on during their teaching by assessing their progress. but surprisingly, exploring their attributes, professional demands, and qualifications has remained a neglected theme i...

15 صفحه اول

S4 : A free electromagnetic solver for layered periodic structures

We describe S4, a free implementation of the Fourier modal method (FMM), which has also been commonly referred to as rigorous coupled wave analysis (RCWA), for simulating electromagnetic propagation through 3D structures with 2D periodicity. We detail design aspects that allow S4 to be a flexible platform for these types of simulations. In particular, we highlight the ability to select differen...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Catalysis Today

سال: 2021

ISSN: ['0920-5861', '1873-4308']

DOI: https://doi.org/10.1016/j.cattod.2020.03.064