Controlling the Band Gap Energy of Cluster-Assembled Materials
نویسندگان
چکیده
منابع مشابه
Synthesis, structure and band gap energy of covalently linked cluster-assembled materials.
We have synthesized a series of cluster assembled materials in which the building blocks are As(7)(3-) clusters linked by group 12 metals, Zn, Cd and Hg, to investigate the effect of covalent linkers on the band gap energy. The synthesized assemblies include zero dimensional assemblies of [Zn(As(7))(2)](4-), [Cd(As(7))(2)](4-), [Hg(2)(As(7))(2)](4-), and [HgAsAs(14)](3-) in which the clusters a...
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ژورنال
عنوان ژورنال: Accounts of Chemical Research
سال: 2013
ISSN: 0001-4842,1520-4898
DOI: 10.1021/ar3002975