Constraining Alteration Processes Along the Siccar Point Group Unconformity, Gale Crater, Mars: Results From the Sample Analysis at Mars Instrument

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چکیده

Abstract Results from the Sample Analysis at Mars‐evolved gas analyzer on board Mars Science Laboratory Curiosity rover constrained alteration history and habitability potential of rocks sampled across Siccar Point unconformity in Gale crater. The Glasgow member (Gm) mudstone just below had evidence acid sulfate or Si‐poor brine Fe‐smectite to Fe amorphous phases, leaching loss Fe‐Mg‐sulfate exchange unfractionated sulfur 34 S (δ = 2‰ ± 7‰) with enriched (20‰ 5‰, Vienna Cañon Diablo Troilite). Carbon abundances did not significantly change (322–661 μgC/g) consistent carbon stabilization by Al‐ Fe‐hydroxide phases. Gm no detectable oxychlorine extremely low nitrate. Nitrate (0.06 wt.% NO 3 ), (0.13 ClO 4 high C (1,472 μg C/g), Fe/Mg‐sulfate concentration (0.24 SO ) depleted −27‰ 7), were detected Stimson formation (Sf) eolian sandstone above unconformity. Redox disequilibrium through detections iron sulfide supported limited aqueous processes Sf sandstone. brines acidic fluids altered but alter underlying mudstones further contact. Chemical differences between suggested that fluid interaction was minimal rocks. These results subsurface after placement. Aqueous along could have provided habitable conditions some cases, N levels heterotrophic microbial populations.

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ژورنال

عنوان ژورنال: Journal Of Geophysical Research: Planets

سال: 2022

ISSN: ['2169-9100', '2169-9097']

DOI: https://doi.org/10.1029/2022je007387