Complex Oscillatory Yielding of Model Hard-Sphere Glasses

Complex oscillatory yielding of model hard-sphere glasses.

The yielding behavior of hard sphere glasses under large-amplitude oscillatory shear has been studied by probing the interplay of Brownian motion and shear-induced diffusion at varying oscillation frequencies. Stress, structure and dynamics are followed by experimental rheology and Browian dynamics simulations. Brownian-motion-assisted cage escape dominates at low frequencies while escape throu...

Supplementary Material for Complex oscillatory yielding of model hard sphere glasses

Yielding of hard-sphere glasses during start-up shear.

Concentrated hard-sphere suspensions and glasses are investigated with rheometry, confocal microscopy, and Brownian dynamics simulations during start-up shear, providing a link between microstructure, dynamics, and rheology. The microstructural anisotropy is manifested in the extension axis where the maximum of the pair-distribution function exhibits a minimum at the stress overshoot. The inter...

Rearrangements in hard-sphere glasses under oscillatory shear strain.

We investigate particle rearrangements in colloidal glasses subjected to oscillatory shear strain by the technique of light scattering (LS) echo. LS echo directly follows the motion of the particles through peaks (echoes) in the intensity autocorrelation function; the height of the peak measures the reversible motion in the sample. Polydisperse hard-sphere poly-methylmethacrylate particles were...

Crystallization of hard-sphere glasses.

We study by molecular dynamics the interplay between arrest and crystallization in hard spheres. For state points in the plane of volume fraction (0.54 <or= varphi <or= 0.63) and polydispersity (0 <or= s <or= 0.085), we delineate states that spontaneously crystallize from those that do not. For noncrystallizing (or precrystallization) samples we find isodiffusivity lines consistent with an idea...