Complex Cation-radical Salts Derived from Phenothiazine and Related Compounds

Chemistry of Iminium Salts and Related Compounds

Chemistry of Iminium Salts and Related Compounds

Phenothiazine Radical Cation Excited States as Super-oxidants for Energy-Demanding Reactions.

We demonstrate that the 10-phenyl-10 H-phenothiazine radical cation (PTZ+•) has a manifold of excited doublet states accessible using visible and near-infrared light that can serve as super-photooxidants with excited-state potentials is excess of +2.1 V vs SCE to power energy demanding oxidation reactions. Photoexcitation of PTZ+• in CH3CN with a 517 nm laser pulse populates a Dn electronically...

Structural Aspects of the Bechgaard Salts and Related Compounds

Structural aspects of the Bechgaard salts (TMTSF)2X and related 2:1 salts. mostly based on the sulfur donors TMTTF and BCPOITF as well as on the hybrid TMDTDSF dorlor, are considered in relationship with their physical properties. The basic structure of these softs is revie~ved with a special emphasize on the dimerization of the organic stack and on the disorder of the aurons IX). 0lhen the den...

Chemistry of Iminium Salts, Imines, and Related Compounds