منابع مشابه
Virial expansion for charged colloids and electrolytes
Using a field-theoretic approach, we derive the first few coefficients of the exact low-density (“virial”) expansion of a binary mixture of positively and negatively charged hard spheres (two-component hard-core plasma, TCPHC). Our calculations are nonperturbative with respect to the diameters d+ and d− and charge valences q+ and q− of positive and negative ions. Consequently, our closed-form e...
متن کاملLiquid-gas separation in colloidal electrolytes.
The liquid-gas transition of an electroneutral mixture of oppositely charged colloids, studied by Monte Carlo simulations, is found in the low-temperature-low-density region. The critical temperature shows a nonmonotonous behavior as a function of the interaction range, kappa(-1), with a maximum at kappasigma approximately 10, implying an island of coexistence in the kappa-rho plane. The system...
متن کاملTunable colloids: control of colloidal phase transitions with tunable interactions
Systems of spherical colloidal particles mimic the thermodynamics of atomic crystals. Control of interparticle interactions in colloids, which has recently begun to be extensively exploited, gives rise to rich phase behaviours as well as crystal structures with nanoscale and micron-scale lattice spacings. This provides model systems in which to study fundamental problems in condensed matter phy...
متن کاملStability of the Liquid Phase in Colloidal Electrolytes
The equilibrium phase diagram of a 1:1 symmetrical mixture composed of oppositely charged colloids is calculated using Monte Carlo simulations. We model the system by the DLVO effective interaction potential. The phase diagram is similar to that of its atomic analog (the ionic fluid), where a liquid-gas first order transition emerges in the low T − ρ regions being stable with respect to crystal...
متن کاملHydrophilic and Hydrophobic Colloids and the Influence of Electrolytes on Membrane Potentials and Cataphoretic Potentials
1. In order to be able to compare the effects of electrolytes on membrane potentials and cataphoretic potentials it seems necessary to distinguish between the charging and depressing effect of electrolytes on these potentials. Only low concentrations of acids and alkalies have a charging effect on the membrane potentials of proteins, while low concentrations of neutral salts have only a depress...
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ژورنال
عنوان ژورنال: Nature
سال: 1921
ISSN: 0028-0836,1476-4687
DOI: 10.1038/107046a0