Clustering of aqueous ethanol solutions. Qualitative approach

Supercritical fluid extraction of ethanol from aqueous solutions

The recovery of ethanol from aqueous solutions was studied by using supercritical carbon dioxide. At 333.2 K and 10.0 MPa, vapor /liquid equilibrium data of the mixture CO2 /ethanol /water were determined. No azeotrope was observed. Theoretical calculation of equilibrium stages was performed and compared with countercurrent column experiments. Separation of extract and solvent was optimized by ...

Influence of Temperature and Ethanol Content on Aggregation of Rhodamine 6g Molecules in Aqueous Ethanol Solutions

The effect of temperature on absorption spectra of Rhodamine 6G at concentrations of 10 and 10 M in water:ethanol solutions of various ethanol content was studied. The dimeric molecular fraction of Rhodamine 6G (10 M) was found as a function of temperature and ethanol content in the aqueous solution. It was shown that the absorption spectrum of Rhodamine 6G dimers (10 M) is dependent on tempera...

The Solubility of Amino Acids and Two Glycine Peptides in Aqueous Ethanol and Dioxane Solutions

The solubilities of amino acids, diglycine, and triglycine have been measured in water and aqueous ethanol as well as dioxane solutions. Free energies of transfer of amino acid side chains and backbone peptide units from water to ethanol and dioxane solutions have been calculated from these data. The results show the similarity between the ‘effects of ethanol and dioxane on the stability of tho...

Hydroxyl Radical-Induced Oxidation of Ethanol in Oxygenated Aqueous Solutions. A Pulse Radiolysis and Product Study

y-Radiolysis of N20-saturated water or photolysis of aqueous H2O2 provided a source of OH radicals. These radicals react with ethanol by preferentially abstracting an H atom at C-l. In the presence of oxygen these radicals are converted into the corresponding peroxyl radicals. The a-hydroxyethylperoxyl radicals decay by first order kinetics (k = ki + k2 [OH -]) acetaldehyde and H02/H+ + 01 bein...

Cr(VI) ADSORPTION – MECHANISTIC APPROACH FOR BIOSORPTION FROM AQUEOUS SOLUTIONS