Closed-loop process for recovery of metals from NdFeB magnets using a trichloride ionic liquid

نویسندگان

چکیده

A solvometallurgical process was developed to recover rare-earth elements and cobalt from end-of-life NdFeB magnets, using the ionic liquid (IL) trihexyltetradecylphosphonium trichloride ([P666,14][Cl3]), or a mixture of [P666,14][Cl3] corresponding chloride IL [P666,14]Cl. The comprises dissolution, stripping regeneration liquid. Pure its with [P666,14]Cl could quantitatively dissolve magnets when solid-to-liquid ratio less than certain threshold value that depended on volume percentage in lixiviant. Increasing temperature 25 50 °C enhanced dissolution rate significantly, but efficiency increased only marginally. had positive effect efficiency. transition metals be removed selectively by two sequential steps, 3 mol∙L−1 NaCl aqueous solution >2 ammonia solutions, respectively. regenerated showed similar fresh

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ژورنال

عنوان ژورنال: Separation and Purification Technology

سال: 2021

ISSN: ['1873-3794', '1383-5866']

DOI: https://doi.org/10.1016/j.seppur.2021.119158