Chemoselective, Postpolymerization Modification of Bioactive, Degradable Polymers
نویسندگان
چکیده
منابع مشابه
Erosion kinetics of hydrolytically degradable polymers.
Degradable polymers are beginning to play an increasing role as materials for environmental and medical applications. Understanding factors that control erosion, such as bond cleavage and the dissolution and diffusion of degradation products, will be critical to the future development of these materials. Erosion kinetics, photomicroscopy, and infrared spectroscopy were used to understand the er...
متن کاملEnd Group Modification of Regioregular Polythiophene through Postpolymerization Functionalization
HT-poly(3-hexylthiophenes) (HT-PHT) with H/Br end group composition were prepared via a modified McCullough method using anhydrous ZnCl2 for the transmetalation step. These bromineterminated HT-PHT can be end group modified at the ω end through a cross-coupling reaction with thienylzinc compounds bearing a THP-protected hydroxy or STABASE-protected amino groups. After deprotection, HT-PHTs with...
متن کاملNew synthetic approaches to prepare degradable polymers
This thesis is concerned with the synthesis of acid labile co-polymers. Two polymer systems were examined (1) polyacetals and (2) poly(ortho esters). As for poly(ortho esters), there is a need for better synthetic methods to prepare these polymers more easily without the need of stringent anhydrous conditions, with more broad structural variation, and in a more cost effective manner. Pendent fu...
متن کاملMultidimensional Vascularized Polymers using Degradable Sacrificial Templates
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 1 wileyonlinelibrary.com and autonomous materials. [ 22–24 ] Porous materials not only mediate transport of fl uids in fi ltration, [ 25 ] but also regulate ion exchange in battery electrodes [ 26 ] and separator fi lms, [ 27 ] facilitate new tissue growth in bioscaffolds, [ 28–31 ] and increase strength-to-weight ratio in structural solids. [ 3...
متن کاملChemical modification of maleic anhydride polymers with carbazole
Maleic anhydride (MAN) copolymers with methyl methacrylate(MMA), ethyl methacrylate(EMA), methyl acrylate(MA), ethyl acrylate (EA) and buthyl acrylate (BA) ( in a 1:1 mole ratio) were synthesized by free radical polymerizations method under vacuum -azobis(isobutironitrile)(AIBN) as an initiator of reaction at 701C. The copolymer compositions were determined using related 1H NMR spectra techni...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Biomacromolecules
سال: 2019
ISSN: 1525-7797,1526-4602
DOI: 10.1021/acs.biomac.8b01631