Chemical synthesis of the tumor-associated globo H antigen

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Chemical Synthesis of the Tumor-Associated Globo H Antigen.

A derivative of the tumor-associated globo H antigen, a complex hexasaccharide, was synthesized by a convergent and efficient [3+2+1] strategy using various glycosylation methods. All glycosylation reactions afforded good to excellent yields and outstanding stereoselectivity, including the installation of cis α-linked D-galactose and L-fucose. The longest linear sequence for this synthesis was ...

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ژورنال

عنوان ژورنال: RSC Advances

سال: 2015

ISSN: 2046-2069

DOI: 10.1039/c5ra00759c