Chemical speciation, bioavailability and risk assessment of potentially toxic metals in soils around petroleum product marketing company as environmental degradation indicators

نویسندگان

چکیده

The study aims at investigating chemical speciation, bioavailability and risk assessment of some selected metals in soils around refined petroleum depot using the concentrations as variables to ascertain impacts activities within depot. Surface-soils (0–15 cm) were collected from premises Pipelines Product Marketing Company, Ibadan, Nigeria, while control samples 200 m away location. Electrical conductivity pH measured a calibrated dual purpose meter, elemental analysis was done Atomic absorption spectroscopy analytical technique. results showed that exhibited low ecological risk; minor enrichment for Mn, moderately severe Ni Co, Cr extremely Pb, Zn Cd. There contamination factor Ni, Cr, Fe moderate by Geo - accumulation index indicated unpolluted with Fe, polluted Pb strongly Inter-element clustering affinity and/or similar genetic origin among elements. Speciation suggested Cd, occurred residual fraction; carbonate fraction, Mn have its highest percentage Fe–Mn oxides fraction. Percentage mobility most are immobile non-bioavailable. Study concluded oil-impacted contaminated metals, but risk.

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ژورنال

عنوان ژورنال: Petroleum Research

سال: 2022

ISSN: ['2524-1729', '2096-2495']

DOI: https://doi.org/10.1016/j.ptlrs.2021.08.006