Charge Fluctuations and the Valence Transition in Yb under Pressure

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Charge fluctuations and the valence transition in Yb under pressure.

We present a dynamical mean-field theory study of the valence transition (f;{14} --> f;{13}) in elemental, metallic Yb under pressure. Our calculations reproduce the observed valence transition as reflected in the volume dependence of the 4f occupation. The transition is advanced by heating, and suggests quasiparticle or Kondo-like structure in the spectra of the trivalent end state, consistent...

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ژورنال

عنوان ژورنال: Physical Review Letters

سال: 2009

ISSN: 0031-9007,1079-7114

DOI: 10.1103/physrevlett.102.246401