C–H Bond activation and C–C bond formation in the reaction of 2,5-dimethylthiophene with TpMe2Ir compounds
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چکیده
منابع مشابه
C-H Bond activation and C-C bond formation in the reaction of 2,5-dimethylthiophene with TpMe2Ir compounds.
The bulky 2,5-dimethylthiophene (2,5-Me2T) reacts at 60 degrees C with TpMe2Ir(C2H4)2 to give a mixture of two TpMe2Ir(III) hydride products, 3 and 4, that contain in addition a thienyl (3) or a thienyl-derived ligand (4). For the generation of 3 only sp2 C-H activation is needed, but the formation of 4 requires also the activation of an sp3 C-H bond and the formation of a new C-C bond (between...
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ژورنال
عنوان ژورنال: Dalton Trans.
سال: 2005
ISSN: 1477-9226,1477-9234
DOI: 10.1039/b419414d